ChemE.info - Chemical Engineering Consulting

One of my strangest (and scariest) experiences was my visit to the SASOL plant at Secunda. This is the largest synthetic fuels plant in the world and is situated on an open grassy plain a few hours drive east of Johannesburg.

My recollection was that my plane arrived in Johannesburg around dawn after an overnight flight from London so I was pretty exhausted and jet-lagged. I had to get a rental car and then drive for hours across the Veldte (on the wrong side of the road… South Africa is an ex-British colony). The scenery was pretty spectacular… Definitely “big sky” country although it was strikingly different from anything I have seen in the US or Australia.

Eventually I arrived at Secunda and that’s where things got surreal. I had been checked into Graceland Hotel Casino & Country Club (see photo). I drove up the sweeping drive surrounded on both sides by a treeless, windswept, and totally empty golf course to the hotel casino itself which was a fantastic thing like something out of a Disney theme park.

Under the entrance portico I was met by a tall, thin black man dressed up as Uncle Sam (all in red, white, and blue satin with a top hat, tail coat, and brightly colored suspenders… Braces if you are from the UK.).

Inside, the theme was 1800’s New Orleans and the Mississippi… The staff were dressed up like saloon keepers with straw boater hats and sleeve garters. The hotel was quite luxurious and new but it seemed very odd to find all this pseudo-Americana in the depths of Africa.

The next morning I drove out the SASOL plant and that also was more than a bit surreal. The synthetic fuel plant had been developed to circumvent the oil embargo imposed by the world community during the apartheid era and, inevitably, was a target for the anti-apartheid guerrillas. On the morning I drove out, a huge thunder storm was drifting in from the west, looming over the plant… And the plant was heavily fortified with armored watch towers. The overall impression that morning was like something out of a high-tech, industrial Lord of the Rings.

This visit took place a few years after the collapse of apartheid. Unfortunately, the end of apartheid has made South Africa, if anything, even more dangerous than when there was an ongoing civil war. All the South African engineers I worked with routinely carried guns when they drove to and from work… There were lockers at the gatehouse where you left you gun while at the plant. As a visitor and not being familiar with the local modus vivendi, I was pretty worried. Rather like a Japanese tourist who got parachuted into the South Bronx or Watts.

I spent about a year at Kennecott Development working on a project for Kennecott’s Carborundum subsidiary (I think Carborundum is now owned by Saint Gobain). We were developing two processes for making boron nitride ceramic fibers. One process was intended to make tensile BN fibers for use in woven composite materials. The second process made a loose BN fiber mat that looked very much like the pink fiberglass mat used in home construction (the BN wasn’t pink of course ;).

What I want to focus on here is the second fiber mat process. One cannot spin Boron Nitride fibers directly so the process involved spinning boron oxide glass fibers first and then nitriding the BO with ammonia to convert it to BN.

As I mentioned, the fiber mat we wanted to end up with looked a lot like fiberglass wall insulation so the BO glass spinning apparatus was modeled on a commercial fiberglass spinning system. This was comprised of an electrically heated metal tank that stored the molten boron oxide glass, a metering valve, a perforated spinning cup, and a torch system.

The molten boron oxide glass was metered into the spinning cup where it was thrown against the side by the centripetal force. It then extruded through the holes in the cup a formed a cloud of glass fibers surrounding the cup. The torch was positioned so that it melted through the fibers once they reached a certain radius from the center of the cup so that one would get a consistent fiber length in the mat.

In the commercial fiberglass system, the torch would have been supplied with either natural gas or propane. But boron oxide glass is very hygroscopic; in other words it soaks up moisture from the air. When exposed to humidity it ends up looking like sticky cotton candy. And, of course, a major combustion product of both natural gas and propane is H2O.

So what to do? We needed a torch fuel that didn’t produce water vapor as a product of combustion. I don’t think it was me that thought of it but somebody on the team came up with a very elegant solution. We used carbon monoxide as the fuel and that worked quite well. It burned hot enough to cut the fibers as needed and the only combustion product was CO2 so we didn’t end up with cotton candy. Neat, eh?